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Official Unicode name: Smirking Face (U+1F60F)
A sly half-smile — confidence, self-satisfaction, or suggestive flirting.
😏 is the universal flirt signal and the face of innuendo. In DMs it implies 'you know what I mean'. It can also be smug: 'called it 😏' after being proven right.
Flirty banter, teasing friends, or celebrating being right. Avoid in professional chats — it almost always reads as suggestive or smug.