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Official Unicode name: Face Exhaling (U+1F62E U+200D 1F4A8)
A face blowing out air — relief, exhaustion, or letting off steam.
😮💨 covers 'whew, that was close', post-stress decompression, and 'she's so fine 😮💨' admiration. Also implies smoking in some contexts.
Relief after deadlines, dramatic sighs, or impressed reactions.